Multiple passwords in keychain: Mac Mail keeps asking for password, then get 'unable to verify password'
This can happen if Mac Mail is more than one entry in Keychain for each in/out entry and it is using the wrong one.
In Utilities:
- Open Keychain Access,
- Use Keychain First Aid under the Keychain Menu item.
Then either check the Password under that item, change it, or delete it and start over.